Polar aprotic solvents (solvents that cannot form hydrogen bonds in solution) do not solvate the nucleophile but rather surround the accompanying cation, thereby raising the ground state energy of the nucleophile. Because the energy of the activated complex is a fixed value, the energy of activation becomes less and, therefore, the rate of reaction increases.
Figure illustrates the effect of solvent polarity on the energy of activation and, thus, the rate of reaction
The smaller activation energy leads to the more rapid reaction.
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